The applicability of the Maximum PowerPoint of Microbial Fuel Cells: Influence of Potential Scan rate and real-time external Load

Abstract

Performance evaluation of a microbial fuel cell (MFC) is usually done with linear sweep voltammetry (LSV) [1] at a given potential scan rate (PSR) [2]. This evaluation does not often reflect the long-term performance of the MFC under real-time external loads [1]. In this study, the performance of a single-chamber MFC was evaluated with three external loads (1206, 470, and 270 Ohms) calculated from LSV maximum power point (MPP) with three PSRs (0.1, 0.5, and 1 mV/s). The estimated power from the MPP in ascending order of PSR were 61.96, 87.88, and 166.68mW/m2 at 116.5, 229.6, and 403 mA/m2, respectively. The average power obtained with 1206, 470, and 270 Ohms in the first two hours of operation were 73 + 16.7, 36.3 + 42, and 88.5 + 120.1 mW/m2 at current densities of 124.6 + 14.3, 121.2 + 73.4, and 232.6 + 176.2 mA/m2, respectively. The result showed that overestimation was more pronounced at higher PSRs. Although the MFC was initially underestimated at 0.1 mV/s, this PSR more accurately reflects the true and applicable estimate of the long-term performance of the MF vC. These results are explicitly beneficial for electrochemical estimation of the actual performance of MFCs under real-time external loads.